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Chile was the largest copper producer Live Gold Prices. Feb 15, 2021 With ~5,700 ktonnes of copper mined in 2020, Chile was the top copper producer worldwide, followed by Peru (2,200 ktonnes) and China (1,700 ktonnes). The top ten copper producing countries mined 15,920 ktonnes of copper in 2020, a 2.3% decline over 2019 (16,289 ktonnes).